The Darbut ophiolite in West Junggar is covered unconformably by sedimentary-volcanic series of Tailegula Formation in Sartohay region. LA-ICP-MS U-Pb dating on zircons from dacite gives the 206Pb/238U weighted mean age of 349±2 Ma, indicating that the Tailegula Formation was formed in Tournaisian of Early Carboniferous. The dacites show right-oriented linear REE patterns with LREE enrichment and negative Eu anomaly. In trace element primitive mantle normalized diagram, the standardized abundance of all samples increase as rising of the element incompatibility. The average Sr, Sr/Y, and La/Yb of dacites in Tailegula Formation are 195 μg/g, 5.2 and 4.6, respectively, much less than those of classic arc dacites and adakites. Combined with low-grade deformation and metamorphism, the dacites in Tailegula Formation are suggested to erupt in rift environment.